The Pole hopes for a career-best performance despite having any warmup matches on grass.
The rivals could meet in the semis, and won't see Djokovic until the final.
The World No.1 faces a few potential minefields in her half of the Wimbledon women's draw.
Big servers John Isner and Nick Kyrgios will deliver insight for ESPN during Wimbledon.
Hall of Famers will receive a cast racquet as a symbol of tennis' ultimate honor.
ESPN's exclusive live Wimbledon coverage in the U.S. begins on July 1 at 6 a.m. on ESPN and ESPN+.
"I don't think any of those [wild card] women can make a big run at Wimbledon," ESPN analyst Patrick McEnroe told Tennis Now.